2-Cyanoquinolin-1-ium hydrogen sulfate

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2-Cyano­quinolin-1-ium hydrogen sulfate

The title salt, C(10)H(7)N(2) (+)·HSO(4) (-), is formed by the transfer of a proton from H(2)SO(4) to the N atom of 2-cyano-quinoline during crystallization. The quinoline ring system is approximately planar with a maximum deviation of 0.013 (3) Å. In the crystal, the cations are linked to the anions via inter-molecular N-H⋯O, O-H⋯O and C-H⋯O hydrogen bonds, forming a layered network.

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In the crystal structure of the title salt hydrate, C9H8NO(+)·HSO4 (-)·H2O, the quinoline N-H atoms are hydrogen bonded to the bis-ulfate anions. The bis-ulfate anions and water mol-ecules are linked together by O-H⋯O hydrogen-bonding inter-actions. The cations and anions form separate layers alternating along the c axis, which are linked by N-H⋯O and O-H⋯O hydrogen bonds into a two-dimensional...

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In the title molecular salt, C(7)H(6)N(3)O(2)S(+)·HSO(4) (-), the 2-amino-6-nitro-1,3-benzothia-zole ring system is essentially planar [mean deviation = 0.0605 (4) Å]. In the crystal, N-H⋯O and O-H⋯O hydrogen-bonding inter-actions result in a layer motif.

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In the title compound, 2C(4)H(6)N(3) (+)·SO(4) (2-), the cations are each essentially planar with r.m.s. deviations of the fitted atoms of 0.008 and 0.002 Å. In the crystal, adjacent ions are linked by N-H⋯O, C-H⋯O and C-H⋯N hydrogen bonds, forming a three-dimensional network.

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In the crystal of the title mol-ecular salt, C(8)H(6)F(3)N(2) (+)·HSO(4) (-), cation-to-anion N-H⋯O hydrogen bonds generate [100] chains. Anion-to-anion O-H⋯O hydrogen bonds generate [001] helices and cross-link the chains into a three-dimensional network.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2010

ISSN: 1600-5368

DOI: 10.1107/s160053681003878x